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[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]-diphenolato}-trinitratocopper(II)lutetium(III)
Jing-Chun Xing1, Yong-Mei Xu, Xiao-Guang Cui
1Department of Anaesthesiology, The Second Affiliated Hospital, Harbin Medical University, Harbin 150081, People's Republic of China.
Abstract:
In the title complex, [CuLu(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) ion is four-coordinated in a square-planar geometry by two O atoms and two N atoms from the deprotonated Schiff base. The Lu(III) ion is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base. A mol-ecule of acetone is present as a solvate.
