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Updated: Jun 1, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
4-Ammonio-2,2,6,6-tetra-methyl-piperidinium bis-(dihydrogen phosphate) monohydrate
Mohamed Lahbib Mrad1, Sameh Akriche, Mohamed Rzaigui
1Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, Tunisia.
Abstract:
In the crystal structure of the title compound, C(9)H(22)N(2) (2+)·2H(2)PO(4) (-)·H(2)O, the H(2)PO(4) (-) anions are hydrogen bonded to each other, forming a ribbon parallel to the b axis. The water mol-ecules connect these ribbons via O-H⋯O hydrogen bonds. The organic cations are attached to the dihydrogen phosphate anions and water mol-ecules through N-H⋯O and C-H⋯O hydrogen bonds, forming an infinite three-dimensional network.
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