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Updated: Jun 1, 2026
06:35
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Tetra-n-propyl-ammonium chloride monohydrate
Summary
The crystal structure of a salt hydrate reveals non-interacting ions. Water molecules bridge chloride ions via hydrogen bonds, forming a unique planar ring structure.
Area of Science:
- Crystallography
- Solid-state chemistry
- Hydrogen bonding
Background:
- Understanding the structural characteristics of salt hydrates is crucial for predicting their physical and chemical properties.
- Investigating the role of water molecules in crystal lattice formation provides insights into intermolecular interactions.
Purpose of the Study:
- To elucidate the crystal structure of the title salt hydrate, C(12)H(28)N(+)·Cl(-)·H(2)O.
- To analyze the hydrogen bonding network and the arrangement of ions and water molecules within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the three-dimensional crystal structure.
- Analysis of bond lengths, bond angles, and intermolecular distances was performed.
Main Results:
- The crystal structure consists of discrete, non-interacting tetrabutylammonium cations (C(12)H(28)N(+)) and chloride anions (Cl(-)).
- Water molecules act as hydrogen bond donors and acceptors, linking two chloride ions through hydrogen bonds.
- A planar, eight-membered ring, {⋯H-O-H⋯Cl}(2), is formed around a center of inversion, involving the water molecule and two chloride ions.
Conclusions:
- The crystal structure is characterized by isolated ions and a specific hydrogen bonding motif involving water.
- The identified planar eight-membered ring represents a significant structural feature of this salt hydrate.
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