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The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Dichloridobis(2-methyl-quinolin-8-olato-κN,O)tin(IV)
1Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Summary
The bis-chelated tin compound [Sn(C(10)H(8)NO)(2)Cl(2)] features a tin atom with a distorted octahedral coordination environment. This structural analysis provides insights into tin-based coordination chemistry.
Area of Science:
- Inorganic chemistry
- Coordination chemistry
- Crystallography
Background:
- Tin compounds exhibit diverse coordination geometries.
- Bis-chelated tin complexes are of interest for their structural and electronic properties.
Purpose of the Study:
- To characterize the coordination environment of the tin atom in the bis-chelated compound [Sn(C(10)H(8)NO)(2)Cl(2)].
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular structure.
- Analysis of bond lengths, angles, and coordination geometry.
Main Results:
- The tin atom is bis-chelated by two 8-quinolinolato ligands.
- The coordination geometry around the tin atom is a distorted cis-Cl(2),cis-N(2),trans-O(2) octahedron.
Conclusions:
- The study elucidates the specific distorted octahedral coordination of tin in this bis-chelated complex.
- This detailed structural information contributes to understanding the stereochemistry of tin coordination compounds.
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