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Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
4-Hydr-oxy-3-[(2E)-3-(3,4,5-trimethoxy-phen-yl)prop-2-eno-yl]-2H-chromen-2-one
Lassaad Mechi1, Samar Chtiba, Naceur Hamdi
1Unité de Chimie des Matériaux, ISSBAT, Université de Tunis-ElManar, 9 Avenue Dr Zoheir SAFI, 1006 Tunis, Tunisia.
Abstract:
A new chalcone of the coumarin, C(21)H(18)O(7), containing an annulated α-pyrone ring, was obtained by condensation of the borate complex of ac-yl(hydr-oxy)coumarin with trimethoxy-benzaldehyde. The structure exhibits intra-molecular hydrogen bonding between the hydroxyl oxygen and the ketonic oxygen in the coumarin group. The bicyclic coumarin fragment and the benzene ring form a dihedral angle of 17.1 (4)°. The crystal packing involves dimers inter-connected by C-H⋯O hydrogen bonding.
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