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Updated: Jun 1, 2026

Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
Published on: April 4, 2014
3,3'-Di-tert-butyl-5,5'-dimethoxy-biphenyl-2,2'-diol
Abstract:
The title compound, C(22)H(30)O(4), displays twofold rotational symmetry. The two benzene rings are almost perpendicular to each other, forming a dihedral angle of 89.8 (6)°. In the crystal, mol-ecules are linked into an extended one-dimensional chain structure via inter-molecular O-H⋯O hydrogen bonds.
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