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Updated: Jun 1, 2026
08:43
Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
Cyclo-hexa-naminium trichloro-acetate.
Summary
Crystal structure analysis reveals that cyclo-hexa-naminium cations and trichloro-acetate anions form hydrogen-bonded R(4)(12) ring motifs. These motifs further assemble into chains along the crystal
Area of Science:
- Crystal engineering and supramolecular chemistry.
- Solid-state chemistry and crystallography.
Background:
- Understanding the self-assembly of organic salts is crucial for designing materials with specific properties.
- Hydrogen bonding plays a key role in directing the formation of ordered structures in crystals.
Purpose of the Study:
- To elucidate the crystal structure of the cyclo-hexa-naminium trichloro-acetate salt.
- To investigate the hydrogen bonding interactions and supramolecular architecture in the solid state.
Main Methods:
- Single-crystal X-ray diffraction analysis.
- Analysis of intermolecular interactions, including hydrogen bonds (N-H⋯O).
Main Results:
- The crystal structure features cyclo-hexa-naminium cations and trichloro-acetate anions.
- Centrosymmetric assemblies of two cations and two anions form R(4)(12) ring motifs via N-H⋯O hydrogen bonds.
- These tetra-meric units are further linked by N-H⋯O interactions into chains propagating along the a axis.
Conclusions:
- The study reveals a specific hydrogen-bonding pattern leading to the formation of novel supramolecular motifs.
- The observed crystal packing highlights the directional nature of N-H⋯O interactions in constructing extended networks.
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