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Updated: Jun 1, 2026

Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyl(tropone)iron
Published on: August 12, 2019
Aqua-chloridobis[5-(2-pyrid-yl)-1H-tetra-zolato-κN]iron(III)
1Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
Abstract:
The title compound, [Fe(C(6)H(4)N(5))(2)Cl(H(2)O)], was synthesized by hydro-thermal reaction of FeCl(3) with 2-(1H-tetra-zol-5-yl)pyridine. The iron(III) metal centre exhibits a distorted octa-hedral coordination geometry provided by four N atoms from two bidentate organic ligands, one water O atom and one chloride anion. The pyridine and tetra-zole rings are nearly coplanar [dihedral angles = 4.32 (15) and 5.04 (14)°]. In the crystal structure, inter-molecular O-H⋯N hydrogen bonds link the complex mol-ecules into a two-dimensional network parallel to (100).
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