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Updated: Jun 1, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
{Bis[2-(diphenyl-phosphino)phen-yl] ether-κP:P'}(dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate-κN:N')copper(I)
Ai-Guo Yu1, Ming Zhang, Guang-Di Yang
1State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, People's Republic of China.
Abstract:
In the title compound, [Cu(C(14)H(12)N(2)O(4))(C(36)H(28)OP(2))]PF(6)·CH(3)CN, the Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2'-biphenyl-4,4'-dicarboxyl-ate ligand and two P atoms from the bis-[2-(diphenyl-phosphino)phen-yl] ether ligand in a distorted tetra-hedral environment. In the cation, the short distance of 3.870 (4) Å between the centroids of the benzene and phenyl rings suggests the existence of intra-molecular π-π inter-actions.
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