Related Experiment Video
Updated: Jun 1, 2026

Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules
Published on: April 28, 2014
Poly[diaqua-(μ(3)-8-oxidoquinoline-5-sulfonato-κN,O:O:O)nickel(II)]
Ying Wang1, Li Wang, Jianing Xu
1Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, People's Republic of China.
Abstract:
In title compound, [Ni(C(9)H(5)NO(4)S)(H(2)O)(2)](n), the Ni(II) atom is coordinated by one N atom and two bridging O atoms from two 8-oxidoquinoline-5-sulfonate ligands, one sulfonate O atom from a third ligand, and two water mol-ecules in a distorted octa-hedral geometry. The two Ni(II) atoms are linked to each other through the bridging O atoms, forming a dimer. Adjacent dimers are connected through the coordination of the sulfonate O atom into a two-dimensional coordination network parallel to (010). Hydrogen bonds between the coordinated water mol-ecules and the uncoordinated O atoms of the sulfonate groups result in the construction of a three-dimensional supra-molecular structure.
Related Concept Videos
Oxidation of Phenols to Quinones
o-hydroxy phenols are oxidized to o-quinones and p-hydroxy phenols to p-quinones. Such redox reactions involve the transfer of two electrons and two protons. The reversible redox property is crucial in...
Formation of Complex Ions
Coordination Compounds and Nomenclature
Diazonium Group Substitution: –OH and –H
Coordination Number and Geometry
Complexometric Titration: Ligands

