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Updated: Jun 1, 2026
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
4-Amino-3-(p-tolyl-oxymeth-yl)-1H-1,2,4-triazole-5(4H)-thione
Abstract:
In the title triazole compound, C(10)H(12)N(4)OS, the triazole ring is essentially planar [maximum deviation = 0.009 (1) Å] and forms a dihedral angle of 5.78 (4)° with the benzene ring. In the crystal structure, mol-ecules are linked into dimers by centrosymmetric N-H⋯S inter-actions. These dimers are linked into two-mol-ecule-wide tapes by N-H⋯N and S⋯S [3.2634 (3) Å] inter-actions. In addition, they are further inter-connected by weak N-H⋯S inter-actions into sheets parallel to the ab plane. The crystal structure is further stabilized by weak inter-molecular C-H⋯π inter-actions.
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