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Updated: Jun 1, 2026
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions
Published on: July 17, 2020
(2R,4R)-2-Hydr-oxy-4-(2-methoxy-phen-yl)bicyclo-[3.3.1]nonan-9-one
Shuping Luo1, Guangcun Zhang, Shuai Zhang
1State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China.
Abstract:
The title compound, C(16)H(20)O(3), contains a bicyclic ring system with two chiral centers. The crystal structure is stabilized by inter-molecular O-H⋯O hydrogen bonds. The absolute configuration was established by the stereo-selectivity of the asymmetric organocatalysis.
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