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Updated: Jun 1, 2026

Protocol for the Synthesis of Ortho-trifluoromethoxylated Aniline Derivatives
Published on: January 19, 2016
1,1-Bis[4-(trifluoro-meth-yl)phen-yl]germetane
Lawrence A Huck1, Gregory D Potter, Hilary A Jenkins
1Department of Chemistry, McMaster University, Hamilton, ON, Canada L8S 4M1.
Abstract:
The inter-nal C-Ge-C bond angle in the germacyclo-butane ring of the title compound, C(17)H(14)F(6)Ge or [Ge(C(3)H(6))(C(7)H(4)F(3))(2)], is 77.8 (3)°. The -CF(3) groups display rotational disorder [occupancies 0.604 (14):0.396 (14) and 0.410 (6):0.411 (6):0.179 (3)] and the germacyclo-butane ring also shows disorder [occupancies 0.604 (14):0.396 (14)].
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