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Updated: Jun 1, 2026
06:46
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
1-(4-Benz-yloxy-5-meth-oxy-2-nitro-phen-yl)ethanone
1Department of Applied Chemistry, College of Science, Nanjing University of Technology, Nanjing 210009, People's Republic of China.
Summary
This study details the molecular structure of a novel organic compound, C(16)H(15)NO(5). It reveals specific intramolecular interactions and how these molecules form chains in their crystal structure.
Area of Science:
- Crystallography
- Organic Chemistry
- Supramolecular Chemistry
Background:
- Understanding molecular interactions is crucial in materials science.
- Crystal packing influences material properties.
- Organic compounds offer diverse structural possibilities.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(16)H(15)NO(5).
- To investigate the nature of intra- and inter-molecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, bond angles, and intermolecular contacts.
Main Results:
- The crystal structure of C(16)H(15)NO(5) was determined.
- A dihedral angle of 74.89(3)° was observed between the aromatic rings.
- Intramolecular C-H⋯O interactions form a seven-membered ring.
- Intermolecular C-H⋯O interactions lead to chain formation along the b axis.
Conclusions:
- The specific arrangement and interactions dictate the compound's solid-state structure.
- The identified interactions provide insights into crystal engineering and molecular assembly.
- This structural information is foundational for potential applications of this organic compound.
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