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(E)-4-Bromo-N'-(2-chloro-benzyl-idene)benzohydrazide
This study details the crystal structure of a novel organic compound, C(14)H(10)BrClN(2)O. Molecules form one-dimensional chains through specific hydrogen bonds, revealing key structural insights.
Area of Science:
- Crystallography
- Organic Chemistry
- Materials Science
Background:
- Understanding the three-dimensional arrangement of atoms in organic molecules is crucial for predicting their properties.
- Crystal structure analysis provides fundamental insights into molecular interactions and solid-state behavior.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(14)H(10)BrClN(2)O.
- To investigate the intermolecular interactions governing the solid-state packing of this molecule.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, bond angles, and dihedral angles provided detailed structural information.
Main Results:
- The dihedral angle between the two benzene rings in C(14)H(10)BrClN(2)O was determined to be 11.4(2)°.
- Intermolecular N-H⋯O hydrogen bonds were identified, linking molecules into chains parallel to the c axis.
Conclusions:
- The crystal structure reveals a specific molecular conformation and packing arrangement driven by hydrogen bonding.
- The observed one-dimensional chain formation is a significant feature of the compound's solid-state architecture.
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