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Updated: Jun 1, 2026
06:46
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(E)-3-[4-(Dec-yloxy)phen-yl]-1-(4-hydroxy-phen-yl)prop-2-en-1-one
Summary
This study details the molecular structure and crystal packing of a novel organic compound. Researchers identified specific conformations and hydrogen bonding patterns influencing its two-dimensional network formation.
Area of Science:
- Organic Chemistry
- Crystallography
- Materials Science
Background:
- Understanding molecular conformation and crystal packing is crucial for predicting material properties.
- Hydrogen bonding plays a significant role in the self-assembly of organic molecules.
Purpose of the Study:
- To elucidate the precise molecular geometry and intermolecular interactions of the title compound C(25)H(32)O(3).
- To investigate the crystal structure and network formation of the compound.
Main Methods:
- Single-crystal X-ray diffraction analysis was employed to determine the three-dimensional structure.
- Analysis of bond lengths, angles, and intermolecular contacts, including hydrogen bonds.
Main Results:
- The enone group was observed in an s-cis conformation, and the alkoxy unit exhibited a planar, trans conformation.
- A dihedral angle of 18.87° was measured between the two benzene rings.
- Intermolecular O-H⋯O and C-H⋯O hydrogen bonds were identified, leading to the formation of a 2D network structure.
Conclusions:
- The specific conformation and hydrogen bonding interactions dictate the crystal packing and network architecture.
- The findings provide fundamental insights into the structure-property relationships of this organic compound.
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
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