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Updated: Jun 1, 2026

Modification and Functionalization of the Guanidine Group by Tailor-made Precursors
Published on: April 27, 2017
2-(Benzo[d]thia-zol-2-ylsulfan-yl)-N-(6-methyl-2-pyrid-yl)acetamide
Abstract:
In the title compound, C(15)H(13)N(3)OS(2), the pyridine ring and the benzo[d]thia-zole unit subtend a dihedral angle of 57.7 (2)°. The length of the C(sp) (2)-S bond [1.7462 (17) Å] is significantly shorter than that of the C(sp) (3)-S bond [1.8133 (18) Å]. The crystal structure is stabilized by intra-molecular N-H⋯N and inter-molecular C-H⋯O and C-H⋯N hydrogen-bond inter-actions. Furthermore, C-H⋯π inter-actions stabilize the crystal packing.
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