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Updated: Jun 1, 2026

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
Published on: May 26, 2019
Bromido(quinolin-8-ol-κN,O)(quinolin-8-olato-κN,O)zinc(II) methanol monosolvate
Abstract:
The title compound, [ZnBr(C(9)H(6)NO)(C(9)H(7)NO)]·CH(3)OH, has its metal atom N,O-chelated by a neutral and a deproton-ated 8-hy-droxy-quinoline ligand. The hy-droxy unit of the neutral ligand is a hydrogen-bond donor to the methanol O atom and the alk-oxy O atom of the monoanionic ligand is a hydrogen-bond acceptor to the methanol O atom. In the crystal, adjacent mol-ecules are linked by these two hydrogen bonds, generating a chain running along the a axis.
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