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Updated: Jun 1, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
catena-Poly[[(5-carb-oxy-2H-1,2,3-triazole-4-carboxyl-ato-κN,O)sodium]-di-μ-aqua-κO:O]
Hai-Yan Liu1, Li-Xin Liu, Jing-Quan Sha
1The Provincial Key Laboratory of Biological Medicine Formulation, School of Pharmacy, Jiamusi University, Jiamusi 154007, People's Republic of China.
Abstract:
In the title coordination polymer, [Na(C(4)H(2)N(3)O(4))(H(2)O)(2)](n), the Na(I) atom is six-coordinated by one O atom and one N atom from a 2H-1,2,3-triazole-4-carb-oxy-5-carboxyl-ate ligand and four O atoms from four water mol-ecules, forming a distorted octa-hedal geometry. The Na(I) atoms are bridged by water mol-ecules into a chain structure along [100]. Inter-molecular N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds connect the chains. An intra-molecular O-H⋯O hydrogen bond between the carboxyl-ate groups is observed.
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