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Updated: Jun 1, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
2-Amino-6-(2,4-dichloro-phen-yl)-4-oxo-3,5-diphenyl-cyclo-hex-2-enecarbonitrile
Abstract:
In the title compound, C(25)H(18)Cl(2)N(2)O, the cyclo-hexene ring has a sofa conformation. All the substituents in the cyclo-hexene ring, except the cyano group (which is axial) occupy equatorial positions. The crystal structure is stabilized through N-H⋯O hydrogen bonds, forming a chain extending along the b axis and through C-H⋯N and C-H⋯Cl inter-actions. It is remarkable that only one of the amino H atoms is involved in hydrogen bonding.
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