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![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
[(1S,2S)-2-(1-{[2-(2-Oxidobenzyl-idene-amino)-cyclo-hex-yl]imino}-eth-yl)phenolato-κO,N,N',O']copper(II)
Nura Suleiman Gwaram1, Hamid Khaledi, Hapipah Mohd Ali
1Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Abstract:
In the title compound, [Cu(C(21)H(22)N(2)O(2))], the cyclo-hexyl ring adopts a chair conformation with the two imine groups linked at equatorial positions. The Cu(II) ion is coordinated by two N atoms and two O atoms from the bis-Schiff base ligand in a slightly distorted square-planar geometry. The dihedral angle between the two benzene rings is 45.89 (9)°. The crystal structure is devoid of any classical hydrogen bonds. However, inter-molecular C-H⋯O inter-actions are present and stabilize the structure.
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