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Updated: Jun 1, 2026
06:46
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(3,4-Dimeth-oxy-phen-yl)(4-fluoro-phen-yl)methanone.
1Department of Quality Detection and Management, Zhengzhou College of Animal Husbandry Engineering, Zhengzhou 450011, People's Republic of China.
Summary
The crystal structure of a fluorinated organic compound reveals a specific dihedral angle between its aromatic rings. Molecules are linked into chains via intermolecular hydrogen bonds in the solid state.
Area of Science:
- Crystallography
- Organic Chemistry
- Solid-State Chemistry
Background:
- Understanding the three-dimensional arrangement of atoms in organic molecules is crucial for predicting their properties.
- Intermolecular interactions, such as hydrogen bonding, significantly influence crystal packing and material characteristics.
Purpose of the Study:
- To determine and analyze the crystal structure of the title compound, C(15)H(13)FO(3).
- To investigate the spatial arrangement and intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to collect diffraction data.
- The crystal structure was solved and refined using standard crystallographic software.
Main Results:
- The crystal structure of C(15)H(13)FO(3) was successfully determined.
- A significant dihedral angle of 52.78(8)° was observed between the two aromatic rings.
- Intermolecular C-H⋯O hydrogen bonds were identified, leading to the formation of molecular chains along the c axis.
Conclusions:
- The study provides detailed crystallographic data for C(15)H(13)FO(3).
- The observed dihedral angle and hydrogen bonding patterns offer insights into the molecule's conformation and solid-state behavior.
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