N'-(4-Hy-droxy-benzyl-idene)thio-phene-2-carbohydrazide.

Area of Science:

• Crystallography
• Organic Chemistry
• Materials Science

Background:

• Understanding the three-dimensional arrangement of atoms in organic molecules is crucial for predicting their properties.
• Intermolecular forces, such as hydrogen bonds, significantly influence crystal packing and material characteristics.

Purpose of the Study:

• To elucidate the crystal structure of the novel organic compound C(12)H(10)N(2)O(2)S.
• To analyze the dihedral angle between the benzene and thiophene rings.
• To investigate the hydrogen bonding network within the crystal lattice.

Main Methods:

• Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
• Analysis of bond lengths, bond angles, and dihedral angles was performed.
• Identification and analysis of intermolecular interactions, including hydrogen bonds.

Main Results:

• The crystal structure of C(12)H(10)N(2)O(2)S was successfully determined.
• A dihedral angle of 23.34(16)° was measured between the benzene and thiophene rings.
• The crystal structure exhibits N-H⋯O and O-H⋯O hydrogen bonds, leading to the formation of (100) sheets.

Conclusions:

• The study provides precise structural data for the title compound.
• The observed dihedral angle offers insights into the conformational preferences of the molecule.
• The identified hydrogen bonding network dictates the supramolecular architecture in the solid state.