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Updated: Jun 1, 2026
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Synthesis and Purification of Iodoaziridines Involving Quantitative Selection of the Optimal Stationary Phase for Chromatography
Published on: May 16, 2014
(E,E)-1-Methyl-2,6-distyrylpyridinium iodide
Summary
This study details the crystal structure of a pyridine derivative, C(22)H(20)N(+)·I(-). It reveals specific dihedral angles and intermolecular pi-pi stacking interactions, confirming E configuration of substituents.
Area of Science:
- Crystallography
- Organic Chemistry
- Supramolecular Chemistry
Background:
- Pyridine derivatives are important in various chemical applications.
- Understanding molecular packing and interactions is crucial for material properties.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(22)H(20)N(+)·I(-).
- To analyze the dihedral angles and intermolecular interactions within the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, bond angles, and intermolecular contacts.
Main Results:
- The crystal structure revealed specific dihedral angles of 15.30° and 11.82° between the pyridine and benzene rings.
- Intermolecular π-π stacking interactions were observed between phenyl and pyridyl rings with a shortest centroid-centroid distance of 3.672 Å.
- The 2,6-distyryl substituents were confirmed to have an E configuration.
Conclusions:
- The study provides a detailed structural characterization of the pyridine derivative.
- The observed π-π stacking interactions suggest potential for self-assembly and material design.
- The defined stereochemistry is important for understanding structure-property relationships.
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