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Bis(1,1,2,2-tetramethyldiphosphane-1,2-dithione-κS,S')gold(I) trifluoro-methane-sulfonate
Christoph E Strasser1, Stephanie Cronje, Helgard G Raubenheimer
1Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland, 7602, South Africa.
Abstract:
In the title compound, [Au(C(4)H(12)P(2)S(2))(2)](CF(3)SO(3)), the gold(I) atom is tightly bonded to two S atoms belonging to different ligand mol-ecules and forms two weaker contacts to the remaining S atoms. The coordination geometry around gold is inter-mediate between linear-dicoordinate and tetra-hedral with an S-Au-S angle of 161.49 (3)°.
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