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Published on: August 28, 2019
Bis(μ-quinoline-2-carboxyl-ato)-κN,O:O;κO:N,O-bis-[(acetato-κO,O')(methanol-κO)lead(II)]
Abstract:
The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated Pb(II) atom is chelated by the acetate anion as well as by the quinoline-2-carboxyl-ate anion. One O atom of the quinoline-2-carboxyl-ate anion bridges two symmetry-related Pb(II) atoms, forming the dinuclear compound. Aside from the six atoms connected to the Pb(II) atom by regular coordination bonds, the structure features a long Pb⋯O inter-action [3.145 (3) Å] that gives rise to a distorted Ψ-square-anti-prismatic geometry at the metal center. The H atom of the methanol is hydrogen bonded to an O atom of the acetate.
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