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Updated: Jun 1, 2026
06:46
Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
(E)-1-(4-Meth-oxy-benzyl-idene)-2-phenyl-hydrazine
Summary
This study details the crystal structure of C(14)H(14)N(2)O, revealing a slight dihedral angle between aromatic rings. Molecular interactions in the crystal lattice involve C-H⋯π and N-H⋯π hydrogen bonds.
Area of Science:
- Crystallography
- Organic Chemistry
- Supramolecular Chemistry
Background:
- Understanding molecular packing and intermolecular forces is crucial in crystal engineering.
- Aromatic ring interactions significantly influence the solid-state properties of organic compounds.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(14)H(14)N(2)O.
- To analyze the dihedral angle between aromatic rings and identify intermolecular interactions in the crystal lattice.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of the crystal structure revealed the dihedral angle and hydrogen bonding patterns.
Main Results:
- The dihedral angle between the aromatic rings in the C(14)H(14)N(2)O molecule was determined to be 9.30(6)°.
- Intermolecular interactions, specifically C-H⋯π and N-H⋯π hydrogen bonds, were identified as the primary forces linking molecules in the crystal.
Conclusions:
- The crystal structure of C(14)H(14)N(2)O is stabilized by a combination of aromatic ring twist and specific hydrogen bonding interactions.
- These findings contribute to the understanding of structure-property relationships in organic crystalline materials.
![Cercosporin-Photocatalyzed [4+1]- and [4+2]-Annulations of Azoalkenes Under Mild Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F60786.jpg&w=3840&q=50)
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