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![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Tetra-μ-acetato-κO:O'-bis-{[4-methyl-N-(4-methyl-phen-yl)pyridin-2-amine-κN]copper(II)}
Zainal A Fairuz1, Zaharah Aiyub, Zanariah Abdullah
1Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
Abstract:
The title complex, [Cu(2)(CH(3)COO)(4)(C(13)H(14)N(2))(2)], features a binuclear mol-ecule, which lies about a crystallographic centre of inversion; the four acetate ions each bridge a pair of Cu(II) atoms. The coordination of the metal atom is distorted octa-hedral within a donor set defined by four O atoms, the heterocyclic N atom and the second Cu atom. The pyridine ring is twisted with respect to the tolyl ring and forms a dihedral angle of 35.34 (9)°. A bifurcated N-H⋯(O,O) hydrogen bond is present, linking the amine group to two carboxyl-ate O atoms derived from different acetate ions. In the crystal, C-H⋯π inter-actions link mol-ecules into a supra-molecular array in the bc plane.
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