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Tricarbon-yl[η-2-(methyl-diphenyl-phosphanium-yl)-1,3,4-triphenylcyclo-penta-dienyl]molybdenum(0)
Tao Xu1, Junwei Ye, Weitao Gong
1State Key Laboratory of Fine Chemicals and School of Chemical Engineering, Dalian University of Technology, Dalian 116012, People's Republic of China.
Abstract:
The title compound, [Mo(C(36)H(29)P)(CO)(3)], contains an Mo(0) atom with a typical piano-stool coordination defined by the phospho-nium cyclo-penta-dienylide ligand η(5)-1-(methyl-diphenyl-phosphanium-yl)-2,3,5-triphenyl-2,4-cyclo-penta-dien-1-yl and by three carbonyl groups. The distance between the Mo(0) atom and the cyclo-penta-dienyl ring is 2.0616 (13) Å.
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