trans-Dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate
Alfred Muller1, Reinout Meijboom
1Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa.
Abstract:
In the title compound, trans-[PdCl(2){P(4-MeOC(6)H(4))(3)}(2)]·C(7)H(8), the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3409 (4) and 2.2981 (4) Å, respectively. An intra-molecular C-H⋯Cl hydrogen bond occurs. In the crystal, weak C-H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules. The toluene solvate molecule is equally disordered over two sets of sites.
![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)

