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Updated: May 2, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Bis{[6-meth-oxy-2-(4-methyl-phen-yl)iminiometh-yl]phenolate-κO,O'}tris-(nitrato-κO,O')europium(III)
1Jinhua College of Vocation and Technology, Jinhua, Zhejiang 321017, People's Republic of China.
Abstract:
The crystal structure of title compound, [Eu(NO(3))(3)(C(15)H(15)NO(2))(2)], contains two Schiff base 6-meth-oxy-2-[(4-methyl-phen-yl)imino-meth-yl]phenolate (L) ligands and three independent nitrate ions that chelate to the europium(III) ion via the O atoms. The coordination number of the Eu(III) ion is ten. The L ligands chelate with a strong Eu-O(deprotonated phenolate) bond and a weak Eu-O(meth-oxy) contact, the latter can be inter-preted as the apices of the bicapped square-anti-prismatic Eu(III) polyhedron. Intra-molecular N-H⋯O hydrogen bonds occur.
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