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Updated: Jun 1, 2026

08:40
Gyroid Nickel Nanostructures from Diblock Copolymer Supramolecules
Published on: April 28, 2014
[meso-Tetra-kis(4-heptyl-oxyphen-yl)porphyrinato]nickel(II)
Abstract:
In the title compound, [Ni(C(72)H(84)N(4)O(4))], the four-coordinate Ni(II) ion in the middle of the planar 24-membered porphyrin ring is located on a crystallograpic inversion center, with Ni-N distances of 1.946 (2)-1.951 (2) Å. The 4-heptyl-oxyphenyl groups are twisted with respect to the porphyrin mean plane, the dihedral angles being 88.5 (3) and 79.1 (2)°.
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