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[Bis(diphenyl-phosphan-yl)dimethyl-silane-κP,P']tetra-carbonyl-chromium(0)
Normen Peulecke1, Stephan Peitz, Bernd H Müller
1Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
Abstract:
The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 80.27 (1)°.
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