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Solid-phase Synthesis of [4.4] Spirocyclic Oximes
Published on: February 6, 2019
3,3,9,9-Tetra-phenyl-2,4,8,10-tetra-oxa-spiro-[5.5]undeca-ne
Xiaoqiang Sun1, Liang Chen, Yan Jiang
1Key Laboratory of Fine Chemical Engineering, Changzhou University, Changzhou 213164, Jiangsu, People's Republic of China.
Abstract:
In the title compound, C(31)H(28)O(4), the asymmetric unit contains two crystallographically independent mol-ecules. In these two mol-ecules, the four dihedral angles between each pair of phenyl rings on the same C atoms are 75.4 (1), 83.0 (1), 85.0 (1) and 80.4 (2)°. All of the nonplanar six-membered heterocycles adopt chair conformations. Inter-molecular C-H⋯π and weak C-H⋯O inter-actions link the mol-ecules and are effective in the stabilization of the crystal structure.
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