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Published on: February 5, 2018
N-Benzyl-pyridin-2-amine
Jun Wang1, Chuntao Dai, Jianhua Nie
1Zhongshan Polytechnic, Zhongshan, Guangdong 528404, People's Republic of China.
Summary
This study investigates the crystal structure of C(12)H(12)N(2), revealing intermolecular hydrogen bonds and C-H⋯π interactions that form a 3D network. These interactions stabilize the crystal structure through dimer formation and network extension.
Area of Science:
- Crystal Engineering
- Supramolecular Chemistry
- Organic Chemistry
Background:
- Understanding intermolecular forces is crucial for designing materials with specific properties.
- Crystal structure analysis provides insights into molecular packing and interactions.
Purpose of the Study:
- To elucidate the crystal structure of the title compound, C(12)H(12)N(2).
- To identify and characterize the intermolecular interactions governing crystal packing.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of hydrogen bonds and C-H⋯π interactions was performed.
Main Results:
- The crystal structure is characterized by intermolecular N-H⋯N hydrogen bonds forming R(2)(2)(8) rings.
- C-H⋯π interactions play a significant role in dimer consolidation and the formation of a 3D network.
- A dihedral angle of 67.2(1)° was observed between the benzyl and pyridyl rings.
Conclusions:
- The crystal packing of C(12)H(12)N(2) is stabilized by a combination of hydrogen bonding and C-H⋯π interactions.
- These interactions lead to the formation of a robust three-dimensional supramolecular architecture.
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