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Updated: Jun 1, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
Published on: September 18, 2016
rac-(1R,2R,4S)-1,2-Dibromo-4-[(1R)-1,2-dibromo-eth-yl]cyclo-hexa-ne
Robert Köppen1, Matthias Koch, Franziska Emmerling
1BAM Federal Institute for Materials Research and Testing, Department Analytical Chemistry, Reference Materials, Richard-Willstätter-Strasse 11, D-12489 Berlin-Adlershof, Germany.
Abstract:
In the title compound, C(8)H(12)Br(4), the cyclo-hexane ring exhibits a chair conformation. The C-Br distances range from 1.964 (6) to 1.985 (5) Å and the C-C distances range from 1.496 (6) to 1.543 (7) Å. Short inter-molecular Br⋯Br contacts [3.467 (4) Å] occur in the crystal.
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