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Updated: Jun 1, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
Published on: August 16, 2018
(2-Amino-phen-yl)(p-tol-yl)methanone
This study analyzes a novel organic compound, C(14)H(13)NO, detailing its molecular structure and hydrogen bonding. The findings reveal specific intra-molecular and inter-molecular interactions crucial for crystal stabilization.
Area of Science:
- Organic Chemistry
- Crystallography
- Molecular Structure Analysis
Background:
- Understanding molecular interactions is key in organic chemistry.
- Crystal structure analysis provides insights into intermolecular forces.
Purpose of the Study:
- To elucidate the molecular structure of the compound C(14)H(13)NO.
- To investigate the hydrogen bonding network within the crystal structure.
- To determine the factors contributing to crystal stabilization.
Main Methods:
- Single-crystal X-ray diffraction was employed to determine the molecular and crystal structure.
- Analysis of bond lengths, bond angles, and dihedral angles.
- Identification and analysis of intra-molecular and inter-molecular hydrogen bonds.
Main Results:
- The compound C(14)H(13)NO exhibits a dihedral angle of 52.8° between its two six-membered rings.
- An intra-molecular hydrogen bond was identified between an amine H atom and a carbonyl O atom.
- Inter-molecular hydrogen bonds of N-H⋯O and C-H⋯N types were observed in the crystal lattice.
Conclusions:
- The observed intra-molecular hydrogen bond influences the conformation of the molecule.
- Inter-molecular hydrogen bonds play a significant role in stabilizing the crystal structure.
- The study provides a detailed structural characterization of C(14)H(13)NO.
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