Enhanced remedial amendment delivery to subsurface using shear thinning fluid and aqueous foam

A major issue with in situ subsurface remediation is the ability to achieve an even spatial distribution of remedial amendments to the contamination zones in an aquifer or vadose zone. Amendment delivery to the aquifer using shear thinning fluid and to the vadose zone using aqueous foam has the potential to enhance the distribution. 2-D saturated flow cell experiments were conducted to evaluate the enhanced fluid sweeping over heterogeneous system, improved contaminant removal, and extended amendment presence in low-permeability zones achieved by shear thinning fluid delivery. Unsaturated column and flow cell experiments were conducted to investigate the improvement on contaminant mobilization mitigation, amendment distribution, and lateral delivery implemented by foam delivery. It was demonstrated that the shear thinning fluid injection enhanced the fluid sweeping and increased the delivery of remedial amendment into low-perm zones. The presence of amendment distributed by the shear thinning fluid in the low-permeability zones was increased. Foam delivery was shown to mitigate the mobilization of highly mobile contaminant from sediments. It also achieved more uniform amendment distribution in a heterogeneous unsaturated system, and demonstrated remarkable increasing in lateral distribution of the injected liquid compared to direct liquid injection.