Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

The Quantum-Mechanical Model of an Atom02:45

The Quantum-Mechanical Model of an Atom

Shortly after de Broglie published his ideas that the electron in a hydrogen atom could be better thought of as being a circular standing wave instead of a particle moving in quantized circular orbits, Erwin Schrödinger extended de Broglie’s work by deriving what is now known as the Schrödinger equation. When Schrödinger applied his equation to hydrogen-like atoms, he was able to reproduce Bohr’s expression for the energy and, thus, the Rydberg formula governing hydrogen spectra. Schrödinger...
¹³C NMR: ¹H–¹³C Decoupling01:04

¹³C NMR: ¹H–¹³C Decoupling

The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
A broadband decoupling technique is used to simplify these complex, sometimes overlapping, signals. Broadband decoupling relies on a...
Atomic Nuclei: Magnetic Resonance01:05

Atomic Nuclei: Magnetic Resonance

The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external magnetic field, as the spins precess at the Larmor frequency, the excess population results in a net magnetization oriented along the z axis. When a pulse or a short burst of radio waves at the Larmor frequency is applied along the x axis, the coupling of frequencies causes resonance and flips the nuclear spins of the excess population from the...
¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.
Atomic Emission Spectroscopy: Interference01:30

Atomic Emission Spectroscopy: Interference

In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
Atomic Nuclei: Larmor Precession Frequency01:11

Atomic Nuclei: Larmor Precession Frequency

The earth's gravitational field produces a 'twisting force' perpendicular to the angular momentum of a spinning mass (such as a spinning top) that causes the mass to 'wobble' around the gravitational field axis in a phenomenon called precession. Similarly, the magnetic moment (μ) of a spinning nucleus precesses due to an external magnetic field directed along the z-axis. The precession of the magnetic moment vector about the magnetic field is called Larmor precession, and the angular frequency...

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Laser-free trapped-ion entangling gates with simultaneous insensitivity to qubit and motional decoherence.

Physical review. A·2026
Same author

Erratum: ^{27}Al^{+} Quantum-Logic Clock with a Systematic Uncertainty below 10^{-18} [Phys. Rev. Lett. 123, 033201 (2019)].

Physical review letters·2023
Same author

Systematic uncertainty due to background-gas collisions in trapped-ion optical clocks.

Physical review. A·2022
Same author

High-fidelity laser-free universal control of trapped ion qubits.

Nature·2021
Same author

Quantum Logic Spectroscopy with Ions in Thermal Motion.

Physical review. X·2021
Same author

State Readout of a Trapped Ion Qubit Using a Trap-Integrated Superconducting Photon Detector.

Physical review letters·2021

Related Experiment Video

Updated: Jun 1, 2026

Generation and Coherent Control of Pulsed Quantum Frequency Combs
06:42

Generation and Coherent Control of Pulsed Quantum Frequency Combs

Published on: June 8, 2018

Quantum coherence between two atoms beyond Q=10(15).

C W Chou1, D B Hume, M J Thorpe

  • 1Time and Frequency Division, National Institute of Standards and Technology, Boulder, Colorado 80305, USA. chinwen@nist.gov

Physical Review Letters
|May 24, 2011
PubMed
Summary
This summary is machine-generated.

Researchers achieved precise frequency comparisons of aluminum ions (Al(+)) using quantum superposition, reaching fractional uncertainties of 3.7×10(-16)/√[τ/s]. This quantum coherence method advances atomic clock accuracy and ion state detection.

More Related Videos

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
07:56

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference

Published on: September 5, 2019

Measurement of Coherence Decay in GaMnAs Using Femtosecond Four-wave Mixing
15:58

Measurement of Coherence Decay in GaMnAs Using Femtosecond Four-wave Mixing

Published on: December 3, 2013

Related Experiment Videos

Last Updated: Jun 1, 2026

Generation and Coherent Control of Pulsed Quantum Frequency Combs
06:42

Generation and Coherent Control of Pulsed Quantum Frequency Combs

Published on: June 8, 2018

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference
07:56

A Photonic System for Generating Unconditional Polarization-Entangled Photons Based on Multiple Quantum Interference

Published on: September 5, 2019

Measurement of Coherence Decay in GaMnAs Using Femtosecond Four-wave Mixing
15:58

Measurement of Coherence Decay in GaMnAs Using Femtosecond Four-wave Mixing

Published on: December 3, 2013

Area of Science:

  • Quantum physics
  • Atomic spectroscopy
  • Ion trap technology

Background:

  • Precise frequency comparisons are crucial for advancing atomic clocks and fundamental physics tests.
  • Maintaining quantum coherence in multi-atom systems is challenging but essential for high-precision measurements.

Purpose of the Study:

  • To develop and demonstrate a novel method for high-precision frequency comparison of two aluminum ions (Al(+)).
  • To leverage quantum coherence for enhanced measurement accuracy beyond probe radiation decoherence.
  • To enable individual quantum state detection in a multi-ion chain without spatial resolution.

Main Methods:

  • Preparing two aluminum ions in quantum superposition states.
  • Observing coherent phase evolution over 3.4×10(15) cycles.
  • Utilizing correlation signals from entangled ions to extract relative phase information.
  • Developing a non-spatial-resolving detection method for individual ion states within a linear ion chain.

Main Results:

  • Achieved a fractional frequency uncertainty of 3.7(-0.8)(+1.0)×10(-16)/√[τ/s] for the frequency comparison of two Al(+) ions.
  • Reported a Q factor derived from quantum coherence of 3.4(-1.1)(+2.4)×10(16).
  • Measured a spectroscopic Q factor of 6.7×10(15) for a Ramsey time of 3 seconds.
  • Successfully demonstrated the detection of individual quantum states of two Al(+) ions in a Mg(+)-Al(+)-Al(+) chain.

Conclusions:

  • Quantum superposition and coherence provide a robust method for high-accuracy frequency comparisons, even after probe decoherence.
  • The demonstrated technique significantly enhances the precision of atomic measurements and the Q factor of quantum systems.
  • The non-spatial-resolving state detection method offers a new capability for complex ion trap systems.