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Synthesis and Characterization of Functionalized Metal-organic Frameworks
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Published on: September 5, 2014

Monofunctionalized pillar[5]arenes: synthesis and supramolecular structure

Tomoki Ogoshi1, Kazuki Demachi, Keisuke Kitajima

  • 1Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. ogoshi@t.kanazawa-u.ac.jp

Chemical Communications (Cambridge, England)
|May 25, 2011
PubMed
Summary

Researchers achieved the first synthesis of monohydroxy pillar[5]arene via controlled de-O-methylation. This intermediate enabled the creation of mono-guest-functionalized pillar[5]arene, forming self-inclusion complexes or undergoing guest dethreading depending on the solvent.

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