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Related Concept Videos

Characteristics and Nomenclature of Homopolymers01:00

Characteristics and Nomenclature of Homopolymers

Polymers that are made up of identical monomer units are called homopolymers. Only one repeating unit is involved in the construction of the homopolymer structure. For example, as depicted in Figure 1, polypropylene is a homopolymer constituted of propylene monomers. Here, the only repeating unit in the polymer chain is propylene.
Polymer Classification: Architecture01:14

Polymer Classification: Architecture

Polymers are classified as linear or branched on the basis of their chain architecture. The polymer chains in linear polymers have a long chain-like structure with minimal to no branching at all. Even if a polymer features large substituent groups on the monomer, which appear as branches to the skeleton, it is not considered a branched polymer. A branched polymer contains secondary polymer chains that arise from the main polymer chain. The branching occurs when the polymer growth shifts from...
Characteristics and Nomenclature of Copolymers01:24

Characteristics and Nomenclature of Copolymers

Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...
Polymer Classification: Stereospecificity01:26

Polymer Classification: Stereospecificity

Polymerization generates chiral centers along the entire backbone of a polymer chain. Accordingly, the stereochemistry of the substituent group has a significant effect on polymer properties. Polymers formed from monosubstituted alkene monomers feature chiral carbons at every alternate position in the polymer backbone. Relative to the predominant orientation of substituents at the adjacent chiral carbons, the polymer can exist in three different configurations: isotactic, syndiotactic, and...
Polymers02:34

Polymers

The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the properties that they exhibit. Additionally,...
Polymers02:34

Polymers

The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the properties that they exhibit. Additionally,...

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Synthesis and Characterization of Self-Assembled Metal-Organic Framework Monolayers Using Polymer-Coated Particles
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Microporous organic polymers: design, synthesis, and function.

Jia-Xing Jiang1, Andrew I Cooper

  • 1Department of Chemistry and Centre for Materials Discovery, University of Liverpool, Crown Street, Liverpool L69 3BX, UK.

Topics in Current Chemistry
|May 28, 2011
PubMed
Summary
This summary is machine-generated.

Microporous organic polymers (MOPs) are versatile materials for catalysis, separations, and gas storage. This review covers MOP synthesis, design, and applications, comparing them to zeolites and metal-organic frameworks.

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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Nanotechnology

Background:

  • Microporous organic polymers (MOPs) are defined as materials with average pore sizes less than 2 nm, composed of light elements like C, H, O, N, and B.
  • MOPs are categorized into amorphous and crystalline groups, offering unique structural properties.

Purpose of the Study:

  • To provide a comprehensive overview of microporous organic polymers (MOPs).
  • To discuss the synthesis, design criteria, and applications of MOPs.
  • To compare MOPs with inorganic zeolites and hybrid metal-organic frameworks.

Main Methods:

  • Review of existing literature on MOPs.
  • Analysis of synthesis strategies and design principles for high surface area and micropore volume.
  • Comparative assessment of MOPs against zeolites and metal-organic frameworks.

Main Results:

  • MOPs offer advantages in applications such as catalysis, separations, and gas storage.
  • Discussion of the trade-offs between MOPs and other porous materials.
  • Identification of potential for discovering new MOPs from existing polymer literature.

Conclusions:

  • MOPs represent a promising class of materials with diverse applications.
  • Further research can unlock new MOP structures and functionalities.
  • MOPs offer a tunable platform for advanced material design.