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Related Concept Videos

Ordinal Level of Measurement00:55

Ordinal Level of Measurement

The way a set of data is measured is called its level of measurement. Correct statistical procedures depend on a researcher being familiar with levels of measurement. For analysis, data are classified into four levels of measurement—nominal, ordinal, interval, and ratio.
Data measured using an ordinal scale are similar to nominal scale data, but there is one major difference. The ordinal scale data can be ordered. An example of ordinal scale data is a list of the top five national parks in the...
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Unlike parametric methods, nonparametric statistics are ideal for nominal and ordinal data, requiring fewer assumptions about the population's nature or distribution. This makes nonparametric methods easier to apply and interpret, as they do not depend on parameters like mean or standard deviation. One common approach in nonparametric analysis is to sort data according to a specific criterion. For instance, we might arrange weather data from hottest to coldest days in a month or rank cities...
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Percentile

A percentile indicates the relative standing of a data value when data are sorted into numerical order from smallest to largest. It represents the percentages of data values that are less than or equal to the pth percentile. For example, 15% of data values are less than or equal to the 15th percentile. Low percentiles always correspond to lower data values. High percentiles always correspond to higher data values.Percentiles divide ordered data into hundredths. To score in the...
Nominal Level of Measurement00:56

Nominal Level of Measurement

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Natural selection influences the frequencies of particular alleles and phenotypes within populations in several different ways. Primarily, natural selection can be directional, stabilizing, or disruptive. Directional selection favors one extreme trait and shifts the population towards that phenotype while selecting against individuals displaying alternate traits. Stabilizing selection favors an intermediate trait with a narrow range of variation. Deviation from the optimal phenotype towards an...
Quantifying and Rejecting Outliers: The Grubbs Test01:02

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Sometimes, a data set can have a recorded numerical observation that greatly  deviates from the rest of the data. Assuming that the data is normally distributed, a statistical method called the Grubbs test can be used to determine whether the observation is truly an outlier.  To perform a two-tailed Grubbs test, first, calculate the absolute difference between the outlier and the mean. Then, calculate the ratio between this difference and the standard deviation of the sample. This number is...

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Selecting Multiple Biomarker Subsets with Similarly Effective Binary Classification Performances
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Published on: October 11, 2018

Selectivity and Related Measures for nth-Order Data.

N J Messick1, J H Kalivas, P M Lang

  • 1Department of Chemistry, Idaho State University, Pocatello, Idaho 83209.

Analytical Chemistry
|May 31, 2011
PubMed
Summary

This study introduces new mathematical tools to create figures of merit for nth-order analytical instruments. These tools enable better assessment of selectivity, net analyte signal, and sensitivity for complex analytical data.

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Area of Science:

  • Analytical Chemistry
  • Chemometrics
  • Instrumental Analysis

Background:

  • Figures of merit are crucial for evaluating analytical instrument suitability.
  • Existing figures of merit are limited to first-order instruments and data.
  • A gap exists in evaluating higher-order (second-order and nth-order) instruments and data.

Purpose of the Study:

  • To develop practical mathematical tools for creating figures of merit for nth-order instrumentation.
  • To define and develop measures for selectivity, net analyte signal, and sensitivity for nth-order data.
  • To address the lack of established figures of merit for complex analytical data.

Main Methods:

  • Development of mathematical tools for nth-order figures of merit.
  • Focus on a local selectivity measure for second-order instrumentation.
  • Validation using simulated and real second-order data from GC-FTIR and LC-PDA.

Main Results:

  • Successful development of practical mathematical tools for nth-order figures of merit.
  • Demonstration of a local selectivity measure for second-order data.
  • Validation of the proposed measures using chromatographic and spectroscopic data.

Conclusions:

  • The developed mathematical tools provide practical means to establish figures of merit for nth-order instruments.
  • These new measures enhance the evaluation of analytical methods dealing with complex, multi-variable data.
  • The study lays the groundwork for broader application of higher-order figures of merit in analytical science.