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Photoluminescence: Applications01:14

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A Silicon-tipped Fiber-optic Sensing Platform with High Resolution and Fast Response
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Development of a room-temperature phosphorescence fiber-optic sensor.

A D Campiglia1, J P Alarie, T Vo-Dinh

  • 1Advanced Monitoring Development Group, Health Sciences Research Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830-6101.

Analytical Chemistry
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A novel fiber-optic sensor utilizing room-temperature phosphorimetry offers sensitive detection of polycyclic aromatic hydrocarbons in water. This method achieves nanogram-per-milliliter detection limits for key environmental pollutants.

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Area of Science:

  • Environmental Chemistry
  • Analytical Chemistry
  • Sensor Technology

Background:

  • Polycyclic aromatic hydrocarbons (PAHs) are significant environmental pollutants.
  • Accurate detection of PAHs in water is crucial for environmental monitoring.
  • Existing analytical methods may require complex sample preparation or specialized equipment.

Purpose of the Study:

  • To develop and validate a new fiber-optic sensor for PAH analysis.
  • To assess the sensor's performance for environmentally relevant PAHs.
  • To demonstrate the sensor's applicability in real-world water samples.

Main Methods:

  • Solid-surface room-temperature phosphorimetry (RTPh) was employed.
  • A fiber-optic sensor platform was designed and fabricated.
  • Analytical figures of merit, including limits of detection and linearity, were determined.
  • The sensor was applied to analyze a contaminated groundwater sample.

Main Results:

  • The sensor demonstrated high sensitivity with limits of detection in the nanograms per milliliter range for multiple PAHs.
  • Analyzed PAHs included pyrene, benzo[e]pyrene, benzo[ghi]perylene, 1,2:3,4-dibenzanthracene, coronene, and 2,3-benzofluorene.
  • The sensor exhibited a fairly linear response, suitable for quantitative analysis.
  • Successful identification of pyrene in a contaminated groundwater sample confirmed its practical feasibility.

Conclusions:

  • The developed fiber-optic sensor is a promising tool for sensitive and quantitative monitoring of PAHs in aqueous environments.
  • The solid-surface RTPh approach offers an efficient alternative for PAH detection.
  • The sensor's performance in real samples highlights its potential for environmental surveillance.