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Building of a novel Mn12 Single Molecule Magnet by assembly of anisotropic {Mn3(μ3-O)(salox)3}+ triangles
Beatriz Cordero1, Olivier Roubeau, Simon J Teat
1Departament de Química Inorgànica, Universitat de Barcelona, Martí i Franqués 1-11, Barcelona, 08028, Spain.
Dalton Transactions (Cambridge, England : 2003)
|June 1, 2011
Abstract:
Assembly of triangular {Mn(III)(3)(O)(salox)(3)}(+) fragments mediated by azido ligands, results in the dodecanuclear [Mn(12)O(4)(salox)(12)(N(3))(4)(MeOH)(4)(H(2)O)(2)] complex with S = 8 ground state and SMM response.
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