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Constructing Thioether/Vinyl Sulfide-tethered Helical Peptides Via Photo-induced Thiol-ene/yne Hydrothiolation
Published on: August 1, 2018
Facile functionalization of polypeptides by thiol-yne photochemistry for biomimetic materials synthesis
Yugang Huang1, Yonghong Zeng, Jianwen Yang
1Institute of Polymer Science, DSAPM Lab, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, GuangZhou, China.
Chemical Communications (Cambridge, England)
|June 1, 2011
Abstract:
Rapid and highly efficient side-chain functionalization of polypeptides was achieved via combination of ring-opening polymerization of a new clickable monomer of γ-propargyl-L-glutamate N-carboxyanhydride (PLG-NCA) and thiol-yne photochemistry, which provides a convenient and universal route to prepare diverse polypeptide-based biomimetic hybrid materials.
