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Published on: January 22, 2017
Microprobe speciation analysis of inorganic solids by fourier transform laser mass spectrometry
K Poels1, L Van Vaeck, R Gijbels
1Department of Chemistry, University of Antwerp, Universiteitsplein 1, B-2610 Wilrijk-Antwerpen, Belgium.
Abstract:
Fourier transform (FT) laser microprobe mass spectrometry (LMMS) aims at the characterization of local constituents at the surface of solids. Signals from structural fragments specify the main building blocks of the analyte while adduct ions, consisting of one or two intact analyte molecules and a stable ion, allow specific identification of the molecule. A series of inorganic reference compounds including binary salts, oxides, and oxy salts was analyzed to assess the FT LMMS capabilities for the determination of the inorganic molecular composition. Compounds from different classes can be tentatively identified by deductive reasoning while those with the same elements in different stoichiometries require comparison with reference spectra.
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