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Updated: Jun 1, 2026

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
Published on: May 9, 2014
Rapid assembly of colloidal monolayer for the synthesis of surface anisotropic particles
Jung Hun Kevin Song1, David Harbottle, Jae W Lee
1Chemical Engineering Department, The City College of New York, Steinman Hall, 140th Street & Convent Avenue, New York, New York 10031, United States.
Abstract:
A facile and efficient technique for synthesizing rapid and large-scale colloidal monolayer is introduced to obtain surface anisotropic particles. Silica particles grafted with long alkyl chains are rapidly organized into monolayer assemblies by implementing water-film climbing and convective particle assembly on glass slides. Assembled particles are modified into surface-anisotropic particles utilizing physical vapor deposition with a magnetically active material. The magnetic hemisphere enables separation of modified and unmodified surface-anisotropic particles. The proposed methodology can lead to a large-scale production opportunity for surface-anisotropic particles.

