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Thorsten Anders1, Kathrin Adamiak, Helmut Keul

  • 1DWI an der RWTH Aachen e.V., and Institute of Technical and Macromolecular Chemistry, RWTH Aachen, Forckenbeckstraße 50, D-52056 Aachen, Germany.

Macromolecular Bioscience
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Compounds bearing two hydroxyl groups are known as diols. When the hydroxyl groups are located on adjacent carbon atoms, the diols are called vicinal diols or glycols. Under acidic conditions, vicinal diols undergo a specific reaction called pinacol rearrangement.
The reaction begins with transferring a proton from the acid catalyst to one of the hydroxyl groups, producing an oxonium ion.