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Updated: May 31, 2026

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Published on: December 3, 2013
Effect of Ga and Mn doping on structural, electrical transport and magnetic properties of Na(0.75)CoO(2)
1Department of Physics, Tsinghua University, Beijing 100084, People's Republic of China. Department of Physics, Yanbian University, Yanji 133002, People's Republic of China.
Abstract:
The effects of doping with magnetic Mn ions or nonmagnetic Ga ions on the structural, electrical transport and magnetic properties of Na(0.75)CoO(2) have been investigated. It has been found that the lattice parameter c of the samples increases with Ga or Mn ion doping. Ga doping raises the electrical resistivity of Na(0.75)CoO(2), but the metallic conducting behaviour of the compound has not been influenced. In contrast, 5% Mn doping leads to a metal-insulator transition at low temperatures in Na(0.75)Co(1-y)Mn(y)O(2). The susceptibility of the Ga doped sample shows strong magnetic field dependence, while the susceptibility of the Mn doped samples is not very sensitive to the magnetic field. This work implies that magnetic interaction plays an important role in Na(x)CoO(2).
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