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Updated: May 31, 2026

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Evidence of structural defect enhanced room-temperature ferromagnetism in Co-doped ZnO
1Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, People's Republic of China.
Abstract:
We report experimentally that room-temperature ferromagnetism of Co-doped ZnO is strongly correlated with structural defects, and that carriers involved in carrier-mediated exchange are by nature by-products of the creation of the defects. On the other hand, the carrier concentration has pronounced influences on the absorption edge in optical transmission spectra of epitaxial Co:ZnO films, in which both a blue-shift and a red-shift are observed. Furthermore, high-temperature annealing results in evolution of the local Co structure from Co(2+) replacing Zn(2+) to a Co(3)O(4)-based phase, which most likely accounts for the transition from ferromagnetism to paramagnetism in the Co:ZnO films.
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